So I took my Photoshop file, sliced it up with the slice tool and then opened it up in Dreamweaver and I've started adding bits of code and extra elements. I've managed to get it to stay centered in the middle of the browser whatever size you make it. Here's what I've got so far.
Design view of home page.
Preview in browser
CSS rules for text.
Super exciting stuff. Think it's looking good so far. I'm just having a little trouble getting the email link to follow the centering of the rest of the page. More code is needed it seems.